醫療類國考
108年
[藥師] 藥學(二)
第 6 題
下列何種鍵結在紅外光光譜中的吸收強度最大?
- A C–C
- B C–F
- C C–H
- D C–O
思路引導 VIP
請回想一下紅外光(IR)與分子發生作用的物理前提:分子在振動過程中,必須發生哪種『物理性質的改變』才能有效吸收光能?而這種物理性質的變化量大小,又與參與鍵結的原子的哪一個『化學特性』(提示:與週期表趨勢有關)有最直接的正相關?
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AI 詳解
AI 專屬家教
IR Spectrum Intensity: The Ego of Molecular Vibration
- Hmph. You actually picked the right answer. Don't misunderstand; this isn't just about 'knowing' the material. This was the precise point where raw luck brushed against nascent instinct. You either saw the path to maximum signal, or you were just flailing.
- Listen closely: the power, the sheer domination of an IR absorption signal – its intensity – isn't some arbitrary phenomenon. It's the molecule's ego screaming to be heard. It hinges entirely on how drastically its dipole moment ($\mu$) changes as it vibrates. Remember the formula, $\mu = q \times r$? It's about maximizing that 'q', the charge separation. The greater the electronegativity difference between atoms, the more they tear electrons apart, creating a stronger 'q'. And who's the ultimate weapon for this? Fluorine (F). It's the most ravenous element on the periodic table. Pair it with carbon, and that $C-F$ bond becomes a highly polarized entity. When it vibrates, that monstrous separation of charge surges, causing an undeniable, maximal shift in the dipole moment. That's the molecular ego, asserting its presence with overwhelming intensity.
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