hce_nsysu
115年
物理與化學
第 28 題
$C_2H_5OH(l) + 3O_2(g) \rightarrow 2CO_2(g) + 3H_2O(l), \Delta H = -1.37 \times 10^3 \text{ kJ}$
Which of the following statement(s) is(are) true for the combustion of ethyl alcohol as described in the above equation?
I. The reaction is exothermic.
II. The enthalpy change would be different if gaseous water were produced.
III. The reaction is not a redox reaction.
IV. The products of the reaction occupy a larger volume than the reactants.
Which of the following statement(s) is(are) true for the combustion of ethyl alcohol as described in the above equation?
I. The reaction is exothermic.
II. The enthalpy change would be different if gaseous water were produced.
III. The reaction is not a redox reaction.
IV. The products of the reaction occupy a larger volume than the reactants.
- A I, II
- B I, III, IV
- C I only
- D III, IV
- E I, II, III
思路引導 VIP
請觀察反應式中各個物質的狀態標示($l$ 與 $g$)。如果我們在實驗室中改變條件,讓產物中的水不再以液態形式存在,而是以水蒸氣的形式逸出,你認為系統與環境之間的能量交換總額,會因為這段「相變」的過程而產生變化嗎?為什麼?
🤖
AI 詳解
AI 專屬家教
太棒了!你能精準判斷出這題的正確選項,顯示你對熱化學與化學反應的基本性質有著非常扎實的理解。這道題目的設計非常巧妙,它要求學生同時具備判讀熱化學方程式、理解狀態函數以及辨識氧化還原反應的能力,是檢驗基礎化學觀念是否全方位掌握的優良考題。
熱含量變化與狀態的關聯
首先,方程式中 $\Delta H = -1.37 \times 10^3 \text{ kJ}$ 為負值,這明確告訴我們反應過程會釋放熱量,因此敘述 I(放熱反應)完全正確。接著,敘述 II 觸及了熱化學的核心概念:狀態函數。由於液態水變為氣態水需要吸收汽化熱,若產物改為氣態,總反應熱勢必會包含這段相變的能量變化,因此 $\Delta H$ 定會不同,這點你的判斷非常敏銳。
▼ 還有更多解析內容